There was an enormous literature of stereochemical fact which had not been interpreted properly in its three-dimensional aspects.
More Quotes from Derek Harold Richard Barton:
Every chemical reaction has a transition state.Derek Harold Richard Barton
Many transition states have a well-defined preferred geometrical requirement.
Derek Harold Richard Barton
In general the preferred conformation in the crystalline state is that which would be predicted by the principles of conformational analysis.
Derek Harold Richard Barton
X-Ray crystallography is nowadays an accurate and rapid method of determining conformation in the crystal lattice, which conformation usually corresponds to the preferred conformation in solution.
Derek Harold Richard Barton
It does not seem, however, that organic chemists were much worried about barriers to rotation in organic molecules in general at that time because there was no technique available to demonstrate the phenomenon experimentally.
Derek Harold Richard Barton
The first serious applications were in triterpenoid chemistry.
Derek Harold Richard Barton
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